snap, crackle, pop

Over the past few months, I've become completely addicted to Nature's Path Flax-Plus brand of pumpkin/flax granola. Seriously addicted. As in, I eat the stuff straight out of the box, no accompanying soy milk, no nothin'. In fact, I have to exercise considerable restraint not to down the entire box over the course of a single day by taking "just a nibble" here and there. I monitor the "stash" in my pantry very closely, and get a bit jittery when the inventory starts to run low. Occasionally I go "cold turkey" for a few weeks, just to prove to myself that I can quit any time. Jen-Luc Piquant suspects the folks at Nature's Path have laced their cereal with crack, but if so, it's Certified Organic (TM) crack, delivered in a tasty, nutritious format.

My addiction might not be the subject of hard-hitting investigative journalism ("Tonight on Hard Copy: people who love their breakfast cereal too much!"), but I'm certainly not alone in my enthusiasm. Americans each consume about 10 pounds -- that's 160 bowls -- of cereal per person every year. (Even Bulgaria is belatedly catching the cereal wave: consumption of breakfast cereal is booming in that country, with Muesli topping the popularity list.) In the US, among the most enduring brands is Kellogg's Rice Krispies, introduced in 1928, which has its very own Website. It also gave rise to that bake sale staple, Rice Krispies Squares which are almost a childhood rite of passage in this country. I certainly have many fond memories of mixing up a batch of the tasty treats with my mother when I was a little girl. The original recipe dates back to 1941 and a Kellogg's employee named Mildred Day, who created it for a Campfire Girls bake sale. There's been umpteen variations on that basic recipe since then, although my favorite remains the fairly straightforward version found on Cooking for Engineers. 

Kellogg's ingenious marketing strategy for the cereal certainly helped boost its enduring popularity, particularly the introduction of three cartoon elfin sprites, appropriately named Snap, Crackle and Pop, after the sound made whenever milk is poured over a bowl of the cereal. Check out this vintage 1950s commercial. Memorable, right? That's why they are instantly recognizable to any American; in fact, in 2002 a pollster found that most Americans can name the three elves but can't name any three of the nine sitting Supreme Court Justices, who clearly need a catchy slogan. Eventually, Kellogg's went global with its marketing slogan: it's "Riks! Raks! Poks!" in Finnish; "Piff! Paff! Puff!" in Swedish; "Pim! Pum! Pam!" in Spanish; and "Knisper! Knasper! Knusper!" in German. It's nice to know that the practice of onomatopoeia is universal. (The sprites are known affectionately to Jen-Luc Piquant as Cric! Crac! and Croc! She categorically denies those tabloid rumors about one wild drunken night in Vegas with the Krispie Krew that ended with her being briefly married to Crackle. Lies. Vicious lies.)

But what is it about Rice Krispies that makes them go snap, crackle, pop? I'm willing to bet it's not microscopic sprites, although research on the topic has admittedly been sparse. It's hardly an urgent scientific question. Nonetheless, a food scientist named Ted Labuza at the University of Minnesota has investigated the matter and come up with a decent explanation for why these popular cereal crisps produce such a distinctive sound. During the cooking process, each piece of rice expands, creating a network of tiny air-filled pockets and tunnels inside the kernel. Add milk, and the cereal starts to absorb the liquid. This puts pressure on the air inside the pockets, causing the "walls" to shatter with a snap, crackle, or a pop. Eventually, of course, the cereal becomes saturated and soggy, and the signature sounds cease.

It's quite a bit like how popcorn pops, which depends on the moisture and starch inside the corn kernel, and the hard shell surrounding it. The moisture percentage in particular must be just right. Heating up the kernels causes the starch granules to expand, thereby increasing the pressure inside the hard shell, which eventually explodes when the pressure gets high enough. And the starch granules expand into the fluffy white globs we know and love. Grains of rice  don't naturally have sufficient moisture, but this is added (via steaming) during the manufacturing process for Rice Krispies, and the grains are then oven-popped to give them their unique texture.

As fascinating as these bits of scientific trivia might be, and as useful as it is for engaging students in classroom science, even Labuza admits, "It's not exactly rocket science." But it's intriguing that, at the molecular level, Rice Krispies essentially behave like glass. Rice Krispies feature strong molecular bonds holding the starch molecules together, and, like glass, if you smashed a rice crisp with a hammer, it would crack and shatter. The fine folks at Molecular Expressions include close-ups of the structure of Rice Krispies at various magnifications in their extensive image gallery; you can see them here. And check out the rest of the site while you're at, since it is stuffed with an embarrassment of riches. We also encourage Labuza to extend his research to investigate why excessive consumption of Cap'n Crunch is so harmful to the roof of one's mouth. Inquiring geek-minds need to know!

Unlike breakfast cereals, glass is an intensive topic of scientific research, because glass is one of those substances known as "amorphous solids," straddling the boundary between solid and liquid phases of matter. (See my prior post on liquid crystals -- another example of amorphous solids -- or on granular media like sand for more information about the various phases of matter.) To wit: In a solid, the molecules arrange themselves in a very precise lattice-type structure, earning them the moniker "crystalline." In fluids, the molecules are disordered rather than rigidly bound, enabling the substance to "flow." Glass falls somewhere in between: the molecules are still rigidly bound, but they are also more disordered than in a pure crystalline solid. So glass is neither, or both: it has its own distinct molecular structure that exhibits properties of both liquids and solids.

These structural properties stem from how glass is made. These days, windows are made by pouring molten glass onto molten tin, and letting it naturally spread out and solidify into a perfectly flat sheet. Older methods were less precise; a few artisans still practice them. You may have seen it at arts and crafts fairs: the glass-blower gets a all of molten glass on the end of a pipe, then blows it into a long, wooden tube-shaped mold. Once the glass has cooled, it's removed from the mold, reheated, and ironed into a single pane. Windows made this way usually contain air bubbles and "waves," and aren't always of perfect thickness throughout.

But what's actually happening as the glass goes from a liquid to an amorphous solid? In a straightforward phase transition, like when water freezes into ice, the transition is dependent on well-defined temperature and pressure points. The glass transition is different: it also depends on the rate at which the heating or cooling takes place. Glass is formed by cooling a liquid below its freezing point, then cooling it some more. Cool it fast enough, in a process known as "super-cooling," and the molecules don't have sufficient time to organize themselves into the rigid crystalline lattice structure of a solid. Instead, as the temperature drops the liquid becomes much more "viscous." (Viscosity is a measure of a liquid's resistance to flow; the higher the viscosity, the greater the resistance.) As this happens, the molecules gradually move more and more slowly, until they are hardly moving at all.

This indecisiveness on the part of glass -- choose a state of matter already! -- has led to the mistaken assumption that glass is actually a fluid. There is an enduring urban legend that the glass windows in medieval cathedrals are thicker at the bottom because over hundreds of years, the glass has "flowed" downward and pooled at the bottom. There is a tiny bit of truth to the legend. At the molecular level, glass does "flow", it just does so very verrry sloooowly. Yvonne Stokes, a mathematician at the University of Adelaide in Australia, has performed detailed  calculations on old cathedral windows, and estimates that it would take at least 10 million years for the glass at the bottom to grow just 5% thicker. She emphasizes that this is a conservative estimate; it might take much longer. So there's frankly no way in hell that the irregularities in medieval cathedral windows are due to the flowing properties of glass. Instead, the observed anomalies are probably due to inherent flaws resulting from the manufacturing process. (For more detailed information on the molecular structure of glass, whether or not it can be said to truly "flow," and some fascinating early history, see this excellent discussion.)

In a 1999 article in Discover magazine on the physics of glass, Robert Kunzig discussed the possibility of an "ideal glass": "what you would produce if you could cool a liquid with geologic slowness while somehow preventing it from crystallizing." It would be a distinct state of matter, rather than the confused hybrid that is so familiar to us: motionless, with a rigid molecular order like a crystal -- except it wouldn't be a crystal. Physicists have no idea how to even begin visualizing such a thing. But it could be important. We've heard whispers to the effect that discovering an ideal glass transition phase -- namely, a point during the supercooling process where the molecules have no choice but to move rapidly from the disordered liquid configuration to a highly-ordered solid configuration -- could yield insights into the structure of the early universe, which may have existed in a similar amorphous disordered state.

Alas, the latest news on that front isn't encouraging. A paper in the June 9 2006 issue of Physical Review Letters, by Princeton University's Salvatore Torquato (et al), concluded that such an ideal glass transition phase doesn't exist. Torquato's team performed a bunch of computer simulations and couldn't find any such well-defined transition point. Torquato told Live Science that "You could have this continuous change from most disordered to most ordered, and there are an infinite number of possible transition phases between these points. It puts another nail in the coffin for [the ideal transition] theory."

Maybe that ideal transition phase is a bit questionable, but the mysterious "Moosino" over at Chi c'e' in Ascolto reports on a very different kind of "transition phase" from amorphous solid into, well, a million little pieces. Apparently she was driving along one day last week, when one of the side windows of her car spontaneously shattered. Being such a well-trained scientist, she nosed around until she found some answers. Basically, the side windows of a car are made of tempered glass, a process that causes the exterior surface to compress while the interior is still expanding a bit. The end result is an exterior compression layer and an interior tension layer -- I believe the technical term is an "inclusion." If a crack develops later on in the compression layer, all the interior tension is released all at once. The window goes snap! Or crackle! Or pop! Just like a bowl of Rice Krispies.

You knew I'd find a way to come full circle, right? And now if you'll excuse me, it's time for my daily "fix" of pumpkin/flax granola. That monkey on my back demands it. But hey, I can quit anytime. Really.

Comments

[Pyracantha]

We can't keep "Nature's Path" pumpkin flax granola on the shelves at Trader Joe's. It gets bought as soon as it is stocked. Sometimes they open up the box and start eating it right there in the store. So you're not alone.

Pyracantha from ELECTRON BLUE (sign designer for Tysons Corner Virginia Trader Joe's)

[Matt]

Just totally by coincidence, I came home to my wife making Rice Krispie treats. I finished the last of the batch before bed -- I seriously have no control with Rice Krispie treats. You and your silly granola "addiction" have nothing on this.

Yummy, yummy, yummy.

[bc]

Enjoy your Nature's Path Flax.

I'll be the guy enjoying the Capt. Crunch over there.

Didn't need Neal Stephenson to tell me about the method for eating them correctly, either. I figured the "consumption window" out all by myself.

Back on John Cusack for a minute, don't forget to see "The Road to Wellville".
It'll change the way you think about Dr. JH Kellogg for better or worse.

bc

[Quasar9]

Hi Jen,
thanks for the snap crackle & pop (corn) lesson.
I'll remember to get a few xtra boxes in when you visit, in case you raid the cupboard at night and there's none left for my break-fast when I rise.

But, you really got my attention going with Glass:
"estimates that it would take at least 10 million years for the glass at the bottom to grow just 5% thicker." - Is that give or take a million years. lol!

"ideal glass": "what you would produce if you could cool a liquid with geologic slowness while somehow preventing it from crystallizing." -
funny, we can make synthetic diamonds in a lab.
but you are right we cannot 'produce' geologic time

I still it is awesome when we say something is 9 billion light years away, that is the distance light would travel in 9 billion years, considering it takes less than three seconds to reach the moon from earth.
Always tempted to ask if anyobody sat there under a tree for 9 billion years counting, even Buddha didn't sit under a tree that long ... and he had a lot of patience

[Quasar9]

Yeah Matt, your wife obviously knows the way to a man's heart, did she make some for the kids too.
I guess if my woman could keep me in rice krispie treats, I would have to overlook all her other short comings - and marry her!

And if I found some by the bedside at night, I'd know I'm in for a treat. lol!

[Matt]

At great peril to my Twisted Physics Father of the Year award, I ate maybe 80% of the Treats. Each of my kids got a full dessert portion, but after everyone goes to bed in my house, I have about four waking hours to try to resist my passions. Sometimes I lose that fight.

[doug]

Regarding the observation that glass in old stained glass windows is on average thicker at the bottom; a very plausible explanation given to me by an experienced stained glass window mechanic points out that glass when it is manufactured in the old way for this purpose; using flattened cylinders as you describe in your essay, guys blowing blowing the cylinders weren't trying to create perfectly even walls to their cylinders. The glass worker takes the clear pieces and cuts them to the pattern and then places them temporarily onto a nearly verticle easle where they can be see how they fit the pattern before they go to the next stage where colors, shading and linear elements (like lettering) can be added by a variety of other processes. Naturally, even on a subconcious level, anyone knows that things are more stable when wider at the base, but the worker is also aware that it will work whether the thicker edge is on the top or on the side, so there would be a natural bias for things to be placed in a more stable orientation if no other design considerations were over-riding the choice.